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Dutch rider Puck Pieterse won shape 4 of nan Tour de France Femmes arsenic wide leader Demi Vollering took 2nd spot successful a photograph finish.
Pieterse vanished nan 122.7km thrust from Valkenburg to Liege successful a clip of 3 hours 12 minutes 28 seconds, arsenic she pipped Vollering connected nan line.
The 22-year-old's triumph was her first successful a roadworthy title and lifted her to 2nd successful nan standings - 22 seconds down her compatriot.
It gave her nan champion young rider's achromatic jersey and nan polka dot climb jersey.
Kasia Niewiadoma of Poland vanished nan shape successful 3rd and she trails Vollering by 34 seconds successful nan wide classification, while Olympic roadworthy title champion Kristen Faulkner of nan United States sits fourth.
Pieterse said: "It's rather unbelievable, actually. To return nan triumph here, successful a sprint against Demi is simply a dream travel true."
Niewiadoma was pinch nan Dutch duo arsenic they entered nan last kilometre of nan title and launched nan dash early pinch nan trio hitting 57km/h aft a hilly day.
However, she peaked excessively soon which allowed Pieterse to unfastened a mini lead arsenic defending champion Vollering near her ain complaint a fraction excessively late.
Thursday's shape 5 is simply a 152.5km level thrust from Bastogne to Amneville arsenic nan title reaches France aft spending nan opening 3 days successful nan Netherlands and Belgium.
Demi Vollering (Ned/SD Worx) 7hrs 40mins 10secs
Puck Pieterse (Ned/Fenix-Deceuninck) + 22secs
Katarzyna Niewiadoma (Pol/Canyon-SRAM) +34secs
Kristen Faulkner (US/EF–Oatly–Cannondale) +47secs
Juliette Labous (Fra/DSM-Firmenich PostNL) +56secs
Pauliena Rooijakkers (Ned/Fenix-Deceuninck) +1min 3secs
Kimberley le Court (Mau/AG-Soudal) +1mins 3secs
Thalita de Jong (Ned/Lotto Dstny) +1mins 4secs
Cedrine Kerbaol (Fra/Ceratizit-WNT) +1mins 4 secs
Shirin van Anrooij (Ned/Lidl–Trek) +1mins 7secs
Selected others
23. Anna Henderson (GB/Team Visma) +1 mins 59
45. Pfeiffer Georgi (GB/DSM-Firmenich PostNL) +6mins 33secs
72. Lizzie Deignan (GB/Lidl-Trek) +10mins 39secs
77. Becky Storrie (GB/DSM-Firmenich PostNL) +11mins 56secs
85. Lizzie Holden (GB/UAE Team ADQ) +14mins 58secs
105. Alice Towers (GB/Canyon–SRAM) +15mins 47secs