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Green jersey holder Wout van Aert had to wantonness nan Vuelta a Espana aft crashing connected shape 16 arsenic Spanish rider Marc Soler won a tricky mountainous stage.
UAE Team Emirates' Soler vanished 18 seconds up of Italian Filippo Zana to declare his shape win.
Meanwhile, wide classification leader Ben O'Connor managed to narrowly cling connected to his advantage complete Primoz Roglic but is now conscionable 5 seconds up successful nan standings.
British rider Max Poole vanished 3rd successful nan stage, narrowly down Zana successful nan duo closest to shape victor Soler.
Van Aert - who had won 3 stages connected this year's circuit - had to wantonness aft a clang pinch astir 48km remaining.
He sewage backmost connected his motorcycle aft crashing into nan hillside connected a descent, but soon pulled up again and clutched his knee arsenic he was tended to successful nan footwear of his team's car.
The Belgian, who won bronze successful nan Paris 2024 Olympic clip trial, was starring nan upland and points classifications.
Wednesday's 141.5km shape 17 is different thrust crossed mean mountains, from Arneuro to Santander.
Stage 16 results
1. Marc Soler (Spa/UAE Team Emirates) 4hrs 44mins 46secs
2. Filippo Zana (Ita/Jayco-Allua) +18secs
3. Max Poole (GB/Team dsm-firmenich-PostNL) +23secs
4. Jay Vine (Aus/UAE Team Emirates) +57secs
5. Ion Izagirre (Spa/Cofidis) +1min 2secs
6. Isaac del Toro (Mex/UAE Team Emirates) +1min 29secs
7. Marco Frigo (Ita/Israel-Premier Tech) +1min 35secs
8. Mattew Riccitello (USA/Israel-Premier Tech) +1min 47secs
9. Enrique Mas (Spa/Movistar) +3mins 54secs
10. Richard Carapaz (Ecu/EF Education-EasyPost) +3mins 54secs
General classification aft Stage 16
1. Ben O'Connor (Aus/Decathlon-AG2R-La Mondiale) 65hrs 9mins
2. Primoz Roglic (Slo/Red Bull - Bora-Hansgrohe) +5secs
3. Enrique Mas (Spa/Movistar) +1min 25secs
4. Richard Carapaz (Ecu/EF Education-EasyPost) +1min 46secs
5. Mikel Landa (Spa/Soudal - Quick-Step) +2mins 18secs)
6. David Gaudu (Fra/Groupama - FDJ) +3mins 48secs
7. Carlos Rodriguez (Spa/Ineos Grenadiers) +3mins 53secs
8. Mattias Skjelmose (Den/Lidl trek) +4mins
9. Florian Lipowitz (Ger/Red Bull - Bora-Hansgrohe) +4mins 27secs
10. Pavel Sivakov (Fra/UAE Team Emirates) +5mins 19secs